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I. V. 36.
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Table. Solubility of potassium cyanide in methanol and
arvcero
I
I
CUCTeMa
mROK,
m KCN,
r/lOO r
(t, °C)
r/lOO r
(t, °C)
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(19,5)
(19,5)
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(15,5)
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co B3BelllCHHbi M 06p a3QOM n OM e llJ,aJIU B rep ­
rzte rronztepzca aanacs aa­
± 0,05 ° C . Caecs
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onpeneneao B npezraapirr ens nsrx 3 Kc rr Cp HM CHTa x . Do
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nepar ypsr onsrra epHJI bTPa C nopncroii rrJIaCTHHKoH.
B cnysae nonnor o paCTBOp CH H5I COJIH npoaozta na
nOBTOpHbIH 3Kc n e p H M c HT C YMCHbiIlCHUCM COOTH O­
means KOnuqeCTB TBep,n:oH H )l(H.D:KOH ¢a3. <1> u nbTP
llI01Ta ,n:OB O,n:UJIU
zro
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onpezrenas M a c cy nepacraopaaureiics T Bep ,n:o H ¢a3bI.
113 )KH.D:KOH ¢a3bI OTrOH5IJIU nozt saxyyxros« pacrso­
pUTeJIb, OCTaTOK ,n:o n O;IH UTeJIb H O Cy lliU JIU non Ba­
J<YYM0M B ar srocrbepe aprona zro rrOCT05lHHOH MaCCbI.
O CT aTOK U orneneanyio raepnyio epa3Y axcrparnpo­
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TBep,n:oH ¢a3e aJIKOrOn5lTbI OTCYTCTBOBaJIU, B 6CH­
30JIbHbIX 3KCTPaKTaX
ax cozrepacaaae onp eaena nn B
nocne npeztaapirre ns uor o
¢opMe K O H T UTp OBa H u eM,
rH.D:pOJIU3a BO,n:OH :
ROK
+ H 20 = R O H + K OH
(2)
K a K BH)I;HO H 3 Ta6JIU QbI, cyM MapHoe KOJlH q e­
CTBO
pacrsopavux
KOMnOHeHTOB COOTBCTCTBYCT JIU ­
'reparypmaxr ,n:aHHbIM
no pacTBopuMOCTU QHaHHCTOro
KaJI U5I 6e3 )"ICTa 06pa30BaHU5I aJIKOr OJI5ITOB.
JIHTEP ATYPA
I. Gail E., Gos S., Kulzer R., Lorosch J., Rubo A., Sauer M.
Inorganic Cyano Compounds. Ullmann' s Encyclopedia of
Industrial Chemistry. Wcinhcim: Wiley-VCH Verlag. 2004 .
2.
BaJIU 6e3 ,n:on OJIH UT CJIh H OH O'IHCTKU .
9
no­
MOCTaTUpyCMylO 51q CH KY,
24,20 (15,5) [3-5]
ocymann
no CTaHAa p THbIM MCTo,n:UKaM [13]. qUCTOTa pacrso­
pareneii no ,n:a H H bIM D KX COCTaBUJla 60JIee 99,8 %
(cO,Ll,Cp )Ka H Ue s onu H C 60nee 0,2 %) . ~UaH H.D: KaJI U5I
((ll. ,Ll,.a .» , O AO «KoPYH,n:», r . JJ;3ep)KHHcK) UCn OJIb 30 ­
nporpersni
MeTO,nOM,
npeasnnana 0,1
,n:aH Ha51 TeMrrepa Ty p a C TO'lHOCTblO
KeN, r/l 00 r
paCTBOpHTeJ15l
(t, 0C)
BCCOBbI M
U3 MepCH H5I MaCChI H e
O p e,n:Ba p UTeJIb H O
M eTa HOJl U rJIUIJ.epUH OqUl..II,aJIU U
BbIIT.
o n p e,nCJI5IJIH no M CTO­
.D:Y [14]. Csreca
xeraaone U rJIHQCp UHe npasenea sr B T a 6 JIu Qc . I'h ­
BeCTHO [7-12 J, qTO aJIKOrOJlU3 HCKOTOpbIX coneii cna­
. Chern.
coneii
opr aaaxe­
CKOM CHHTe 3e [1 J. Il pn :3T OM saaca oe anaxea a e npa­
o6pe-raKlT naa nsre 06 nx paCTBopUMOCTU B none H
Opr aHHqeCKUX paCTBOpUTeJI5IX . B mrrepar ype UMe­
44. N 9.
. Comp.
PaCTBopUMOCTb
MeTaJIJIOB llIHpOKO UC­
nOJlb3YKlTC5I B QBCTH OH MeTaJI JIypruu H B
X11MlliI 1-1 Xl1J\.1WffiCKASI TEXHOJIOrn5I 20 11 TOM 54 ssm. 9
272 p.
HOBbIH crrpaao-nrax XlfMHKa U TeXIlOJIOra. OCHoBHble CBOH­
CTBa HeOpraHW!eCKHX, opraHW!eCKHX H 3JIeMeHTOOpraJ:lWIe­
CKHX coe.n:HHcHlll1 / Ilozt pen, H.K. Cxaopuos a. CIT6.: ABO
HITO <<MH:p H cesrsa». 2002. 1280 c.;
III
-
3.
4.
5.
6.
7 .
8.
9 .
~
"
­
10 . P la tonov A.Y u., Evdokimov A.N., Kunin A.V.,
Maiyor ova H.D. II J. C hern. Eng. Data . 2002. V. 47. N 5,
P. 1175-1176.
I !. Platonov A.Y., Kurzin A. V., Evdokimov A.N. /I J.
Solution Chern. 2010. V. 39 . N 3. P . 335-342.
12. E nAoh:m fOB A.H., KYP31111 A.B., M 3HOp OB3 E.)].., Ilnaro­
HOB A.IO., C na a rcon A.A., 1.IIICToKllcTOB B.H. IIaTeHf P<!J
NQ 2 178402 . 2002;
Evdokimov A.N., Kunin A. V., Maiyorova E. D., Platoncs
A.Yu., Sivak ov A .A., Chistokletov V.N. Patent RF ~
2178402. 2002 (i n Russian).
13. T opnou A., cI>oPJI. P . Crryn mx XHMI1Ka . <I>113MKO-XMMWle·
CKMe CBoHcTBa, MeTO.JJ:l1Kl1, 0I16JIl1orpa¢ llil. M .: MHp. 1976,
544 c.;
Gordon A.J., F ord R.A. The Ch emist's Comp anion. A
Handbook of Practical Data , Techniques, and References,
New York: Wiley. 1972 . 423 p.
14 . llOJITOpaUKH" r .M., cI> p aH'IYK BJi., K YP311l1 A.B., EBJ\O'
KHMOB A.a II 113B. By30B. XHMllil 11 XMM. TeXHOJIOfllll,
2010. T. 53 . Bsm, 3. C . 154-155;
P olt or ats ki y G .M ., F r anchuk V.B., Kurzin A.V"
Evdokim ov A.N. II lz v. V yssh. Uchebn. Za ved. Khim
Kh im. Tekhnol. 2010. V. 53. N 3. P. 154-155 (in Russian).
Ne w ha nd book for chemis t and tech nologist. M ain pro pe rties
of inorganic, organic and ele rnento-organ ic co mpo unds . Ed.
N.K. Skvortsov.. Saint Pe tersb urg: A NO NPO «Mi r i
Se rnya». 2002 . 1280 p. (in Ru ssian).
Seidell A., Linke W.F. Solub ilities of Inorganic, Metal
Or ganic and O rganic Compounds. Princet on: Van Nostrand
Co. 1940 .1 211 p.
Koran B.li., cI>p1mMall B.M., Ka41apon B.B. Crrpaa oxaax
rro paCTBOpl1MOCTIl .T . I. Kanra 1. M .- JI.: AKa.n:eMIDl a ay«
CCCP. 1961. 960 c.;
Kogan V.B ., Fridman V.M., Kafarov V.V. Handbook on
sol ub ility. V. I. Book 1. M .- L. : Ak ade miya Nauk SS SR.
1961. 960 p. (in Russian).
Stephen H., Stephen T. Solubilities of Inorgani c and
Organic Compone nts. London : Pergamon Press. 1979 . 855 p.
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1074 ;
Ossendovskiy A.M. II Zh. Ru ss. Fiz. Khi m. Ob sch . 190 6.
V. 37 . P. 1071- 1074 (in Russian).
Lod er D..J., Lee D.D. ITaTCIIT CIlIA NQ2278550. 1942;
Loder D..J., Lee D.D. U.S. Patent N 2278 550 . 1942.
Turova N.Ya., Novoselo va A.V. II Rus s. Chern. Rev. 1965.
V. 34. N 3. P. 16 1-1 85 .
Bradley D. C. II Prog. Inor g. Ch ern. 1960. V. 2. P. 303- 361.
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